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Duncan was born in 1910, the eldest child of John MacLeod and Marion Munro of Glen House on 9 Ruisgarry. He was a pupil at Berneray School between 1916 and 1923. Following his father's death in 1922, he moved with his mother and brothers to 5 Lochportain, North Uist in 1924.
Duncan later married Flora MacKay and settled in Leverburgh.